Copper-catalyzed oxidative oxyalkylation of enol ethers with α-amino carbonyl compounds and hydroperoxides.
نویسندگان
چکیده
A new copper-catalyzed oxidative difunctionalization of enol ethers with α-amino carbonyl compounds and hydroperoxides is developed. This method is experimentally simple while allowing for regioselective access to 2-amino-3,4-dioxy carbonyl compounds in good yields, and represents the first example of alkene oxyalkylation through C(sp(3))-H functionalization.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 56 شماره
صفحات -
تاریخ انتشار 2015